Preparation, characterization of mixed-valence antimony-tin phosphomolybdic polyoxometalates and application in the cyclohexanone oxidation in the presence of hydrogen peroxide
In this work, a series of polyoxometalates (POMs), as soluble salts of formula Sn1.5PMo12O40, SbPMo12O40 and $\mathrm{H}_{3-x}\mathrm{Sn}_{x1}\mathrm{Sb}_{x2}\mathrm{PMo}_{12} \mathrm{O}_{40}$ ($x=2x_{1}+3x_{2}$ and $x_{1}$, $x_{2}=$ 0–0.75) were synthesized using the cationic exchange method under...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2022-09-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.195/ |