Kinetics of ethylene polymerization over titanium-magnesium catalysts: The reasons for the observed second order of polymerization rate with respect to ethylene

The data on the effect of ethylene concentration on polymerization rate for several modifications of modern highly active titanium–magnesium catalysts TiCl4/MgCl2 are presented. These catalysts differ in titanium content and conditions of support preparation, activities, and the shape of kinetic cur...

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Bibliographic Details
Main Authors: Mikhail Matsko, Vladimir Zakharov, Marina Nikolaeva, Tatiana Mikenas
Format: Article
Language:English
Published: Iran Polymer and Petrochemical Institute 2015-01-01
Series:Polyolefins Journal
Subjects:
Online Access:http://poj.ippi.ac.ir/article_1112_2dbf1bade85875e0d6ab52c858c7687d.pdf