Electrochemically modified Corey–Fuchs reaction for the synthesis of arylalkynes. The case of 2-(2,2-dibromovinyl)naphthalene

Electrochemically modified Corey–Fuchs reaction for the synthesis of arylalkynes. The case of 2-(2,2-dibromovinyl)naphthalene

The electrochemical reduction of 2-(2,2-dibromovinyl)naphthalene in a DMF solution (Pt cathode) yields selectively 2-ethynylnaphthalene or 2-(bromoethynyl)naphthalene in high yields, depending on the electrolysis conditions. In particular, by simply changing the working potential and the supporting...

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Bibliographic Details
Main Authors: Fabiana Pandolfi, Isabella Chiarotto, Marta Feroci
Format: Article
Language:English
Published: Beilstein-Institut 2018-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
arylalkyne
carbon–bromine bond cleavage
cathodic reduction
Corey–Fuchs reaction
2-(2,2-dibromovinyl)naphthalene
Online Access:https://doi.org/10.3762/bjoc.14.76

Internet

https://doi.org/10.3762/bjoc.14.76

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