Diastereo-selective synthesis of CF3-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide
The first example for the generation of 2,2,2-trifluoroethylidene ylide from corresponding iodonium salt is reported, which has been successfully applied in the epoxidation of aldehydes, achieving the corresponding trifluoromethylated epoxides in high yields and diastereo-selectivities.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co. Ltd.
2023-11-01
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| Series: | Green Synthesis and Catalysis |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666554922000771 |