Ruthenium redox equilibria: 2. Thermodynamic analysis of disproportionation and comproportionation conditions

The key property of Frost diagram has been confirmed using thermodynamic and linear algebra methods. On the basis of the thermodynamic data, the areas of thermodynamic stability of ruthenium chemical species in different valence states as a function of pH for each degree of oxidation have been deter...

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Bibliographic Details
Main Authors: Igor Povar, Oxana Spinu
Format: Article
Language:English
Published: International Association of Physical Chemists (IAPC) 2016-04-01
Series:Journal of Electrochemical Science and Engineering
Subjects:
Online Access:http://pub.iapchem.org/ojs/index.php/JESE/article/view/228