Shining light on the microscopic resonant mechanism responsible for cavity-mediated chemical reactivity
Hybridization of dark optical cavity modes with vibrational states of molecules can alter chemical reactions. Here, the authors use ab-initio methods to shine light on the associated mechanism and highlight the role of the optical mode to redistribute the vibrational energy.
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35363-6 |