Site-selective cobalt substitution in La–Co co-substituted magnetoplumbite-type ferrites: 59Co-NMR and DFT calculation study

The La–Co co-substituted magnetoplumbite-type (M-type) ferrites A Fe _12 O _19 ( A = Ca, Sr and Ba, ion sizes Ca ^2+ $\lt$ Sr ^2+ $\lt$ Ba ^2+ ) with Co compositions around 0.2 have been subjected to ^59 Co-NMR. The results show that Co occupies the 4f _1 , 2a and 12k sites, and that the smaller the...

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Bibliographic Details
Main Authors: Hiroyuki Nakamura, Hiroto Ohta, Ryuya Kobayashi, Takeshi Waki, Yoshikazu Tabata, Hidekazu Ikeno, Christian Mény
Format: Article
Language:English
Published: IOP Publishing 2024-01-01
Series:JPhys Materials
Subjects:
Online Access:https://doi.org/10.1088/2515-7639/ad3b6d