High-temperature Spin Crossover of a Solvent-Free Iron(II) Complex with the Linear Hexadentate Ligand [Fe(L<sub>2-3-2</sub><sup>Ph</sup>)](AsF<sub>6</sub>)<sub>2</sub> (L<sub>2-3-2</sub><sup>Ph</sup> = bis[<i>N</i>-(1-Phenyl-1<i>H</i>-1,2,3-triazol-4-yl)methylidene-2-aminoethyl]-1,3-propanediamine)

High-temperature Spin Crossover of a Solvent-Free Iron(II) Complex with the Linear Hexadentate Ligand [Fe(L<sub>2-3-2</sub><sup>Ph</sup>)](AsF<sub>6</sub>)<sub>2</sub> (L<sub>2-3-2</sub><sup>Ph</sup> = bis[<i>N</i>-(1-Phenyl-1<i>H</i>-1,2,3-triazol-4-yl)methylidene-2-aminoethyl]-1,3-propanediamine)

A novel mononuclear iron(II) complex with a linear hexadentate N<sub>6</sub> ligand, containing two 1,2,3-triazole moieties, [Fe(L<sub>2-3-2</sub><sup>Ph</sup>)](AsF<sub>6</sub>)<sub>2</sub> (<b>1</b>), was synthesized (L<sub...

Full description

Bibliographic Details
Main Author: Hiroaki Hagiwara
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Magnetochemistry
Subjects:
spin crossover
iron(II)
mononuclear
1,2,3-triazole
linear hexadentate ligand
spin transition
magnetism
calorimetry
crystal structure
Online Access:https://www.mdpi.com/2312-7481/5/1/10

Internet

https://www.mdpi.com/2312-7481/5/1/10

Similar Items