Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide

Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide

The diphenyl sulfoxide-catalyzed conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a sulfurous (IV)-catalysis manifold in which diphenyl sulfoxide turnover is achieved using oxalyl chloride as a consumable reagent.

Bibliographic Details
Main Authors: I. A. Gorbunova, D. A. Shipilovskikh, S. A. Shipilovskikh
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2021-12-01
Series:Chimica Techno Acta
Subjects:
aldehydes
lewis base catalysis
organocatalysis
diphenyl sulfoxide
Online Access:https://chimicatechnoacta.ru/article/view/5433

Internet

https://chimicatechnoacta.ru/article/view/5433

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