Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex

Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex

Reactions of isocyanates/isothiocyanates with primary and secondary phosphines without solvent at room temperature afforded phosphinecarboxamide/phosphinecarbothioamide, respectively, in excellent yields. Furthermore, palladium complex Pd(COD)Cl<sub>2</sub> was allowed to react with Ph&l...

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Bibliographic Details
Main Authors: Masumi Itazaki, Kento Okabayashi, Takanari Matsutani, Tomoya Nochida, Toshiyuki Moriuchi, Hiroshi Nakazawa
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Molecules
Subjects:
hydrophosphination
phosphinecarboxamide
phosphinecarbothioamide
palladium(II) complex
hydrogen bond
<i>cis/trans</i> isomerization
Online Access:https://www.mdpi.com/1420-3049/27/17/5564

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https://www.mdpi.com/1420-3049/27/17/5564

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