Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu3N@Ih-C80

Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu3N@Ih-C80

Photochemical carbosilylation of Lu3N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the...

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Bibliographic Details
Main Authors: Masahiro Kako, Kazuya Minami, Taiki Kuroiwa, Shinpei Fukazawa, Yuki Arikawa, Michio Yamada, Yutaka Maeda, Qiao-Zhi Li, Shigeru Nagase, Takeshi Akasaka
Format: Article
Language:English
Published: MDPI AG 2017-05-01
Series:Molecules
Subjects:
endohedral metallofullerene
Lu3N@Ih-C80
carbosilylation
silirane
redox property
Online Access:http://www.mdpi.com/1420-3049/22/5/850

Internet

http://www.mdpi.com/1420-3049/22/5/850

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