Synthesis of Cyclic <i>N</i>-Acyl Amidines by [3 + 2] Cycloaddition of <i>N</i>-Silyl Enamines and Activated Acyl Azides

Synthesis of Cyclic <i>N</i>-Acyl Amidines by [3 + 2] Cycloaddition of <i>N</i>-Silyl Enamines and Activated Acyl Azides

In this study, we describe the synthesis of cyclic <i>N</i>-acyl amidines from readily available <i>N</i>-heteroarenes. The synthetic methodology utilized the versatile <i>N</i>-silyl enamine intermediates from the hydrosilylation of <i>N</i>-heteroare...

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Bibliographic Details
Main Authors: Dong Geun Jo, Changeun Kim, Sinjae Lee, Sooyeon Yun, Seewon Joung
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Molecules
Subjects:
[3 + 2] cycloaddition
<i>N</i>-silyl enamine
B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>
tetrahydroisoquinoline
acyl azide
spectroscopic analysis
Online Access:https://www.mdpi.com/1420-3049/27/5/1696

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https://www.mdpi.com/1420-3049/27/5/1696

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