Synthesis and Properties of Twisted and Helical Azulene Oligomers and Azulene‐Based Polycyclic Hydrocarbons

Synthesis and Properties of Twisted and Helical Azulene Oligomers and Azulene‐Based Polycyclic Hydrocarbons

Abstract The construction of 1,2‐position‐connected azulene oligomers was achieved. In the crystal packing structure of the terazulene, two molecules of (Ra)‐ and (Sa)‐configurations formed a pair. Variable temperature NMR measurements and theoretical calculations of the quaterazulene suggest that t...

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Bibliographic Details
Main Authors: Prof. Dr. Takahiro Tsuchiya, Makoto Higashibeppu, Prof. Dr. Yasuhiro Mazaki
Format: Article
Language:English
Published: Wiley-VCH 2023-11-01
Series:ChemistryOpen
Subjects:
antiaromaticity
azulenes
helical structure
oligomers
polycyclic hydrocarbons
Online Access:https://doi.org/10.1002/open.202100298

Internet

https://doi.org/10.1002/open.202100298

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