Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Bibliographic Details
Main Authors: Tomoya Miura, Tsuneaki Biyajima, Takeharu Toyoshima, Masahiro Murakami
Format: Article
Language:English
Published: Beilstein-Institut 2011-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.7.67