Au<sub>30</sub>(P<i><sup>i</sup></i>Pr<sub>2</sub><i><sup>n</sup></i>Bu)<sub>12</sub>Cl<sub>6</sub>—An Open Cluster Provides Insight into the Influence of the Sterical Demand of the Phosphine Ligand in the Formation of Metalloid Gold Clusters

Au<sub>30</sub>(P<i><sup>i</sup></i>Pr<sub>2</sub><i><sup>n</sup></i>Bu)<sub>12</sub>Cl<sub>6</sub>—An Open Cluster Provides Insight into the Influence of the Sterical Demand of the Phosphine Ligand in the Formation of Metalloid Gold Clusters

Phosphine-stabilized gold clusters are an important subgroup of metalloid gold cluster compounds and are important model compounds for nanoparticles. Although there are numerous gold clusters with different phosphine ligands, the effect of phosphine on cluster formation and structure remains unclear...

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Bibliographic Details
Main Authors: Markus Strienz, Andreas Schnepf
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Molecules
Subjects:
gold cluster
cluster formation
phosphine ligand
X-ray structure
cluster transformation
steric effect
Online Access:https://www.mdpi.com/1420-3049/29/2/286

Internet

https://www.mdpi.com/1420-3049/29/2/286

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