Oxidative fragmentations of 5-hydroxy-1-oxo-5alpha-cholestan-3beta-yl acetate
5-Hydroxy-1-oxo-5a-cholestan-3b-yl acetate (11) was prepared in 5 steps starting from (E)-3b-acetoxy-5,10-seco-1(10)-cholesten-5-one (6). Treatment of the 1-oxo-5-hydroxy derivative 11 with lead tetraacetate (LTA) (under thermal or hypoiodite conditions) or with mercuric oxide/iodine (HgO/I2) reagen...
| Main Authors: | , , , |
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| 格式: | 文件 |
| 语言: | English |
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Serbian Chemical Society
2003-11-01
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| 丛编: | Journal of the Serbian Chemical Society |
| 主题: | |
| 在线阅读: | http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-01.pdf |