The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data also suggest the presence of an inverse-trans-effec...

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Bibliographic Details
Main Authors: Matthew Gregson, Erli Lu, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Christoph Hennig, Andreas C. Scheinost, Jonathan McMaster, William Lewis, Alexander J. Blake, Andrew Kerridge, Stephen T. Liddle
Format: Article
Language:English
Published: Nature Portfolio 2017-02-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms14137

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https://doi.org/10.1038/ncomms14137

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