Synthesis of a Highly Functionalized Triquinane: Studies Towards a Total Synthesis of Subergorgic Acid and Its Analogues
Reaction of enone (11) with the bifunctional Grignard reagent (7) in the presence of copper(I) bromide – dimethyl sulfide, followed by intramolecular alkylation of the resultant chloroketone (15) gave the tricyclic ketone (12). The tricyclic ketone (12) was transformed into the angular triquina...
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| Format: | Article |
| Language: | English |
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MDPI AG
2000-04-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/5/4/674/ |