Derivatives of the triaminoguanidinium ion, 5. Acylation of triaminoguanidines leading to symmetrical tris(acylamino)guanidines and mesoionic 1,2,4-triazolium-3-aminides

Derivatives of the triaminoguanidinium ion, 5. Acylation of triaminoguanidines leading to symmetrical tris(acylamino)guanidines and mesoionic 1,2,4-triazolium-3-aminides

Depending on the reaction conditions, N,N’,N’’-tris(benzylamino)guanidinium salts can react with carboxylic acid chlorides to form either symmetrical N,N’,N’’-tris(N-acyl-N-benzylamido)guanidines 6 or mesoionic 4-amino-1,2,4-triazolium-3-hydrazinides 7. The latter were converted into 1,2,4-triazoliu...

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Bibliographic Details
Main Authors: Jan Szabo, Julian Greiner, Gerhard Maas
Format: Article
Language:English
Published: Beilstein-Institut 2017-03-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
guanidines
mesoionic compounds
triaminoguanidinium salts
1,2,4-triazolium-3-aminides
Online Access:https://doi.org/10.3762/bjoc.13.57

Internet

https://doi.org/10.3762/bjoc.13.57

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