Organic molecules with inverted singlet-triplet gaps

According to Hund’s multiplicity rule, the energy of the lowest excited triplet state (T1) is always lower than that of the lowest excited singlet state (S1) in organic molecules, resulting in a positive singlet-triplet energy gap (ΔEST). Therefore, the up-converted reverse intersystem crossing (RIS...

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Bibliographic Details
Main Authors: Jie Li, Zhi Li, Hui Liu, Heqi Gong, Jincheng Zhang, Yali Yao, Qiang Guo
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-08-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2022.999856/full