Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...

Full description

Bibliographic Details
Main Authors: Elizabeth P. Wildman, Gábor Balázs, Ashley J. Wooles, Manfred Scheer, Stephen T. Liddle
Format: Article
Language:English
Published: Nature Portfolio 2017-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms14769