Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2017-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms14769 |
| _version_ | 1818857967726886912 |
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| author | Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle |
| author_facet | Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle |
| author_sort | Elizabeth P. Wildman |
| collection | DOAJ |
| description | Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages. |
| first_indexed | 2024-12-19T08:48:48Z |
| format | Article |
| id | doaj.art-f709b23a7f1e474d822dea1f9b44a9dc |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T08:48:48Z |
| publishDate | 2017-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f709b23a7f1e474d822dea1f9b44a9dc2022-12-21T20:28:48ZengNature PortfolioNature Communications2041-17232017-03-01811910.1038/ncomms14769Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifsElizabeth P. Wildman0Gábor Balázs1Ashley J. Wooles2Manfred Scheer3Stephen T. Liddle4School of Chemistry, The University of ManchesterInstitute of Inorganic Chemistry, University of RegensburgSchool of Chemistry, The University of ManchesterInstitute of Inorganic Chemistry, University of RegensburgSchool of Chemistry, The University of ManchesterAdvances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.https://doi.org/10.1038/ncomms14769 |
| spellingShingle | Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs Nature Communications |
| title | Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
| title_full | Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
| title_fullStr | Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
| title_full_unstemmed | Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
| title_short | Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
| title_sort | triamidoamine thorium arsenic complexes with parent arsenide arsinidiide and arsenido structural motifs |
| url | https://doi.org/10.1038/ncomms14769 |
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