Comparative study of kinetics isomerization of substituted polyacetylene (Cl, F, Br and I): Semi empirical RM1 study
The newly semi empirical RM1 was used to investigate the interconversions of substituted (F, Cl, Br and I) polyacetylene conformers in the vapor phase. The rates of this geometrical isomerization have been measured and the Arrhenius parameters evaluated. In the case of unsubstituted polyacetylene as...
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| Format: | Article |
| Language: | English |
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Elsevier
2015-03-01
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| Series: | Journal of Saudi Chemical Society |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610312000117 |