Experimental and Theoretical Study of Cyclic Amine Catalysed Urethane Formation

Experimental and Theoretical Study of Cyclic Amine Catalysed Urethane Formation

The alcoholysis of phenyl isocyanate (PhNCO) using stoichiometric butan-1-ol (BuOH) in acetonitrile in the presence of different cyclic amine catalysts was examined using a combined kinetic and mechanistic approach. The molecular mechanism of urethane formation without and in the presence of cyclic...

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Bibliographic Details
Main Authors: Hadeer Q. Waleed, Dániel Pecsmány, Marcell Csécsi, László Farkas, Béla Viskolcz, Zsolt Fejes, Béla Fiser
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Polymers
Subjects:
amine catalysts
kinetics
catalyst free
composite method
ab initio
Online Access:https://www.mdpi.com/2073-4360/14/14/2859

Internet

https://www.mdpi.com/2073-4360/14/14/2859

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