Stereoselective Syntheses of Protected Amino-hydroxy-cyclopentane-carbaldehyde Derivatives from 7-Oxabicyclo[2.2.1]hept-5-en-2-yl Systems
Cycloaddition of azido formates to the double bond of 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives gave mixtures of triazolines that could be separated by chromatography. Their acid-catalyzed dediazoniations generate 7-oxabicyclo[2.2.1]hept-2-yl cation intermediates that rearrange into th...
| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1990-10-01
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| Series: | CHIMIA |
| Online Access: | https://ojs.chimia.ch/chimia/article/view/1957 |