A Concise, Catalyst-Free Synthesis of Davis’ Oxaziridines using Sodium Hypochlorite

A Concise, Catalyst-Free Synthesis of Davis’ Oxaziridines using Sodium Hypochlorite

Abstract N-Sulfonyloxaziridines (Davis’ oxaziridines) can be synthesized by reacting the corresponding N-sulfonylimines with aqueous sodium hypochlorite in acetonitrile without any catalyst. The pH of the aqueous sodium hypochlorite is crucial to obtain the product in high yield. Optimi...

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Bibliographic Details
Main Authors: Saori Kitagawa, Hiromitsu Mori, Tatsuya Odagiri, Katsuya Suzuki, You Kikkawa, Rie Osugi, Shinobu Takizawa, Yoshikazu Kimura, Masayuki Kirihara
Format: Article
Language:English
Published: Georg Thieme Verlag KG 2019-01-01
Series:SynOpen
Subjects:
oxaziridine
davis’ oxaziridine
sodium hypochlorite
sodium hypochlorite pentahydrate
n-sulfonylimine
oxidation
Online Access:http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611722

Internet

http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611722

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