Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil

This study investigates the effect of degumming process and catalyst type on physiochemical and biodiesel properties of tropical-almond (Terminalia catappa) seed oil (TCSO) extracted via mechanical pressing and solvent extraction method. The oil was degummed using 4% citric acid in amount of 10% by...

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Main Authors: L Sani, V.O. Ajibola, S.E. Abechi
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2019-01-01
Series:Journal of Applied Sciences and Environmental Management
Subjects:
Online Access:https://www.ajol.info/index.php/jasem/article/view/181840
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author L Sani
V.O. Ajibola
S.E. Abechi
author_facet L Sani
V.O. Ajibola
S.E. Abechi
author_sort L Sani
collection DOAJ
description This study investigates the effect of degumming process and catalyst type on physiochemical and biodiesel properties of tropical-almond (Terminalia catappa) seed oil (TCSO) extracted via mechanical pressing and solvent extraction method. The oil was degummed using 4% citric acid in amount of 10% by volume of the oil to reduce the acid value, ash content, and water and sediment value of the degummed oil compared to the raw oil. Data obtained show that degumming process reduces the acid value, ash content and water and sediment value from 7.57 mg KOH/g, 0.86 %w/w and 2.48% to 3.82 mg KOH/g, 0.65 %w/w and 2.40% respectively, and the percentage oil yield was 56.30±1.50%. Biodiesel was produced using a two-step reaction system from raw and degummed TCSO catalyzed by NaOH, KOH and CaO/Al2O3. The process yielded a higher yield (97.20±0.35) of biodiesel from degummed oil catalyzed by CaO/Al2O3. The fuel properties of the biodiesels were found to fulfill both ASTM D6751 and EN14214 biodiesel standard except the raw biodiesel. this study confirm that degumming process improves the susceptibility of oil for biodiesel production and that heterogeneous base catalyst produce higher yield and quality fuel than their homogenous counterpart. Keywords: Degummed, Transeterification, Biodiesel, Catalyst, Raw oil, unsaturation
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spelling doaj.art-f9057c8c6d214aa28c713354c4645c9f2024-04-02T19:51:15ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992019-01-01221210.4314/jasem.v22i12.7Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oilL SaniV.O. AjibolaS.E. Abechi This study investigates the effect of degumming process and catalyst type on physiochemical and biodiesel properties of tropical-almond (Terminalia catappa) seed oil (TCSO) extracted via mechanical pressing and solvent extraction method. The oil was degummed using 4% citric acid in amount of 10% by volume of the oil to reduce the acid value, ash content, and water and sediment value of the degummed oil compared to the raw oil. Data obtained show that degumming process reduces the acid value, ash content and water and sediment value from 7.57 mg KOH/g, 0.86 %w/w and 2.48% to 3.82 mg KOH/g, 0.65 %w/w and 2.40% respectively, and the percentage oil yield was 56.30±1.50%. Biodiesel was produced using a two-step reaction system from raw and degummed TCSO catalyzed by NaOH, KOH and CaO/Al2O3. The process yielded a higher yield (97.20±0.35) of biodiesel from degummed oil catalyzed by CaO/Al2O3. The fuel properties of the biodiesels were found to fulfill both ASTM D6751 and EN14214 biodiesel standard except the raw biodiesel. this study confirm that degumming process improves the susceptibility of oil for biodiesel production and that heterogeneous base catalyst produce higher yield and quality fuel than their homogenous counterpart. Keywords: Degummed, Transeterification, Biodiesel, Catalyst, Raw oil, unsaturation https://www.ajol.info/index.php/jasem/article/view/181840DegummedTranseterificationBiodieselCatalystRaw oilunsaturation
spellingShingle L Sani
V.O. Ajibola
S.E. Abechi
Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
Journal of Applied Sciences and Environmental Management
Degummed
Transeterification
Biodiesel
Catalyst
Raw oil
unsaturation
title Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
title_full Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
title_fullStr Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
title_full_unstemmed Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
title_short Effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical-almond (<i>Terminalia catappa</i>) seed oil
title_sort effect of degumming and catalyst type on physiochemical and biodiesel properties of tropical almond i terminalia catappa i seed oil
topic Degummed
Transeterification
Biodiesel
Catalyst
Raw oil
unsaturation
url https://www.ajol.info/index.php/jasem/article/view/181840
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AT voajibola effectofdegummingandcatalysttypeonphysiochemicalandbiodieselpropertiesoftropicalalmonditerminaliacatappaiseedoil
AT seabechi effectofdegummingandcatalysttypeonphysiochemicalandbiodieselpropertiesoftropicalalmonditerminaliacatappaiseedoil