Synthesis and crystal structure of bis(9-mesityl-9,10-dihydro-10-aza-9-borabenzo[h]quinolinato-κ2N1,N10)zinc(II)

Synthesis and crystal structure of bis(9-mesityl-9,10-dihydro-10-aza-9-borabenzo[h]quinolinato-κ2N1,N10)zinc(II)

The title compound, [Zn(C20H18BN2)2] (ZnL2), is an overall uncharged chelate that consists of two units of an NH-deprotonated 10-aza-9-borabenzo[h]quinoline ligand (L) per ZnII center. It was synthesized in two steps by treating the protonated ligand HL with lithium bis(trimethylsilyl)amide and furt...

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Bibliographic Details
Main Authors: Yannik Appiarius, Pim Puylaert, Anne Staubitz
Format: Article
Language:English
Published: International Union of Crystallography 2023-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
1,2-azaborinine
boron-nitrogen
zinc
bidentate ligand
hirshfeld analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023009192

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http://scripts.iucr.org/cgi-bin/paper?S2056989023009192

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