Enthalpies of Combustion and Formation of Severely Crowded Methyl-Substituted 1,3-dioxanes. The Magnitudes of 2,4- and 4,6-diaxial Me,Me-Interactions and the Chair–2,5-twist Energy Difference

Enthalpies of Combustion and Formation of Severely Crowded Methyl-Substituted 1,3-dioxanes. The Magnitudes of 2,4- and 4,6-diaxial Me,Me-Interactions and the Chair–2,5-twist Energy Difference

Enthalpies of combustion of 2,2-<i>trans</i>-4,6- (<b>1</b>) and 4,4,6,6-tetramethyl- (<b>2</b>) and 2,4,4,6,6- (<b>3</b>) and 2,2,4,4,6-pentamethyl-1,3-dioxanes (<b>4</b>) were determined to estimate their enthalpies of formation in the ga...

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Bibliographic Details
Main Authors: Kalevi Pihlaja, Henri Kivelä, Pirjo Vainiotalo, William V. Steele
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Molecules
Subjects:
crowded 1,3-dioxanes
enthalpies of combustion
enthalpies of formation
chair-2,5-twist energy difference
syn-axial Me,Me-interactions
Online Access:https://www.mdpi.com/1420-3049/25/12/2762

Internet

https://www.mdpi.com/1420-3049/25/12/2762

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