Structural and Magnetic Analysis of a Family of Structurally Related Iron(III)-Oxo Clusters of Metal Nuclearity Fe<sub>8</sub>, Fe<sub>12</sub>Ca<sub>4</sub>, and Fe<sub>12</sub>La<sub>4</sub>

Structural and Magnetic Analysis of a Family of Structurally Related Iron(III)-Oxo Clusters of Metal Nuclearity Fe<sub>8</sub>, Fe<sub>12</sub>Ca<sub>4</sub>, and Fe<sub>12</sub>La<sub>4</sub>

The synthesis, crystal structure, and magnetic characterization are reported for three new structurally related iron(III) compounds (NHEt<sub>3</sub>)[Fe<sub>8</sub>O<sub>5</sub>(OH)<sub>5</sub>(O<sub>2</sub>PPh<sub>2</sub>)<...

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Bibliographic Details
Main Authors: Alok P. Singh, ChristiAnna L. Brantley, Kenneth Hong Kit Lee, Khalil A. Abboud, Juan E. Peralta, George Christou
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Chemistry
Subjects:
iron-oxo clusters
molecular magnetism
pseudo-carboxylates
exchange interactions
density functional theory
magnetostructural correlation
Online Access:https://www.mdpi.com/2624-8549/5/3/110

Internet

https://www.mdpi.com/2624-8549/5/3/110

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