Metallacyclobutadienes: Intramolecular Rearrangement from Kinetic to Thermodynamic Isomers

Metallacyclobutadienes: Intramolecular Rearrangement from Kinetic to Thermodynamic Isomers

Abstract Metallacyclobutadienes (MCBDs) are key intermediates of alkyne metathesis reactions. There are in principle two isomerization pathway from kinetic to thermodynamic MCBDs, intermolecular and intramolecular. However, systems that simultaneously isolate two kinds of MCBD isomers have not been...

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Bibliographic Details
Main Authors: Yuanting Cai, Yuhui Hua, Zhengyu Lu, Jiangxi Chen, Dafa Chen, Haiping Xia
Format: Article
Language:English
Published: Wiley 2024-10-01
Series:Advanced Science
Subjects:
intramolecular rearrangement
kinetic isomer
metallacyclobutadiene
metallatetrahedrane
thermodynamic isomer
Online Access:https://doi.org/10.1002/advs.202403940

Internet

https://doi.org/10.1002/advs.202403940

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