Vibrationally mediated photodissociation dynamics of pyrrole

We investigate photodissociation of vibrationally excited pyrrole molecules in a velocity map imaging experiment with IR excitation of N–H bond stretching vibration v1 = 1, νIR= 3532 cm−1, and UV photodissociation at λUV= 243 nm. In the IR+UV experiment, the H-fragment signal is enhanced with respec...

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Bibliographic Details
Main Authors: Kateryna Grygoryeva, Jozef Rakovský, Ivo S. Vinklárek, Ondřej Votava, Michal Fárník, Viktoriya Poterya
Format: Article
Language:English
Published: AIP Publishing LLC 2019-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5091974