Evaluation of 3,3′-Triazolyl Biisoquinoline <i>N</i>,<i>N′</i>-Dioxide Catalysts for Asymmetric Hydrosilylation of Hydrazones with Trichlorosilane

Evaluation of 3,3′-Triazolyl Biisoquinoline <i>N</i>,<i>N′</i>-Dioxide Catalysts for Asymmetric Hydrosilylation of Hydrazones with Trichlorosilane

A new class of axial-chiral biisoquinoline <i>N</i>,<i>N′</i>-dioxides was evaluated as catalysts for the enantioselective hydrosilylation of acyl hydrazones with trichlorosilane. While these catalysts provided poor to moderate reactivity and enantioselectivity, this study re...

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Bibliographic Details
Main Authors: Shiyu Sun, Changgong Xu, Jamielyn Jarvis, Phillip Nader, Brandon Naumann, Abigail Soliven, Roberto Peverati, Norito Takenaka
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Catalysts
Subjects:
Lewis base catalysis
trichlorosilane
hydrosilylation
hydrazone
computational chemistry
Online Access:https://www.mdpi.com/2073-4344/11/9/1103

Internet

https://www.mdpi.com/2073-4344/11/9/1103

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