X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal–Organic Cage with Alkynes as Safe Carbene Precursors

A facile and efficient methodology for the generation of the C-X (X = Si, B) bond through a carbene insertion process was demonstrated using a dirhodium metal–organic cage, MOC-Rh-<b>1</b>, as a heterogeneous catalyst. A series of functionalized alkynes were utilized as safe carbene prec...

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Bibliographic Details
Main Authors: Lianfen Chen, Chaoyi Zhao, Weixian Mo, Chunsheng Li, Xiaoming Lin
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/2/608