Crystal structure of catena-poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

Crystal structure of catena-poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

In the title polymeric complex, {[Fe(CN)2(C10H8N2)2(H2O)2][Au(CN)2]}n, the FeII ion, which is located on a twofold rotation axis, has a slightly distorted FeN4O2 octahedral geometry. It is coordinated by two phenylpyrazine molecules, two water molecules and two dicyanoaurate anions, the Au atom also...

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Bibliographic Details
Main Authors: Olesia I. Kucheriv, Diana D. Barakhtii, Sergey O. Malinkin, Sergiu Shova, Il'ya A. Gural'skiy
Format: Article
Language:English
Published: International Union of Crystallography 2019-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polymeric complex
iron(II) complex
2-phenylpyrazine
dicyanoaurate
aurophillic interactions
offset π–π interactions
supramolecular metal–organic framework
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019009678

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http://scripts.iucr.org/cgi-bin/paper?S2056989019009678

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