An unexpected rhenium(IV)–rhenium(VII) salt: [Co(NH3)6]3[ReVIIO4][ReIVF6]4·6H2O

An unexpected rhenium(IV)–rhenium(VII) salt: [Co(NH3)6]3[ReVIIO4][ReIVF6]4·6H2O

The title hydrated salt, tris[hexaamminecobalt(III)] tetraoxidorhenate(VII) tetrakis[hexafluoridorhenate(IV)] hexahydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octahedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetrahedral [Re...

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Bibliographic Details
Main Authors: James Louis–Jean, Samundeeswari Mariappan Balasekaran, Adelheid Hagenbach, Frederic Poineau
Format: Article
Language:English
Published: International Union of Crystallography 2019-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hexamine-cobalt
perrhenate
hexafluororhenate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019009757

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http://scripts.iucr.org/cgi-bin/paper?S2056989019009757

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