Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride

Electroforming-free resistive switching random access memory (RRAM) devices employing magnesium fluoride (MgF<sub>x</sub>) as the resistive switching layer are reported. The electroforming-free MgF<sub>x</sub> based RRAM devices exhibit bipolar SET/RESET operational character...

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Main Authors: Nayan C. Das, Minjae Kim, Jarnardhanan R. Rani, Sung-Min Hong, Jae-Hyung Jang
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/12/9/1049
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author Nayan C. Das
Minjae Kim
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
author_facet Nayan C. Das
Minjae Kim
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
author_sort Nayan C. Das
collection DOAJ
description Electroforming-free resistive switching random access memory (RRAM) devices employing magnesium fluoride (MgF<sub>x</sub>) as the resistive switching layer are reported. The electroforming-free MgF<sub>x</sub> based RRAM devices exhibit bipolar SET/RESET operational characteristics with an on/off ratio higher than 10<sup>2</sup> and good data retention of >10<sup>4</sup> s. The resistive switching mechanism in the Ti/MgF<sub>x</sub>/Pt devices combines two processes as well as trap-controlled space charge limited conduction (SCLC), which is governed by pre-existing defects of fluoride vacancies in the bulk MgF<sub>x</sub> layer. In addition, filamentary switching mode at the interface between the MgF<sub>x</sub> and Ti layers is assisted by O–H group-related defects on the surface of the active layer.
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spelling doaj.art-fe5988e3d5f847c09f3f52d5878887362023-11-22T14:15:48ZengMDPI AGMicromachines2072-666X2021-08-01129104910.3390/mi12091049Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium FluorideNayan C. Das0Minjae Kim1Jarnardhanan R. Rani2Sung-Min Hong3Jae-Hyung Jang4School of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, KoreaSchool of Energy Technology, Korea Institute of Energy Technology, Naju 58330, KoreaElectroforming-free resistive switching random access memory (RRAM) devices employing magnesium fluoride (MgF<sub>x</sub>) as the resistive switching layer are reported. The electroforming-free MgF<sub>x</sub> based RRAM devices exhibit bipolar SET/RESET operational characteristics with an on/off ratio higher than 10<sup>2</sup> and good data retention of >10<sup>4</sup> s. The resistive switching mechanism in the Ti/MgF<sub>x</sub>/Pt devices combines two processes as well as trap-controlled space charge limited conduction (SCLC), which is governed by pre-existing defects of fluoride vacancies in the bulk MgF<sub>x</sub> layer. In addition, filamentary switching mode at the interface between the MgF<sub>x</sub> and Ti layers is assisted by O–H group-related defects on the surface of the active layer.https://www.mdpi.com/2072-666X/12/9/1049electroforming-freebipolarRRAMfilamentary switchinginterface
spellingShingle Nayan C. Das
Minjae Kim
Jarnardhanan R. Rani
Sung-Min Hong
Jae-Hyung Jang
Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
Micromachines
electroforming-free
bipolar
RRAM
filamentary switching
interface
title Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
title_full Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
title_fullStr Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
title_full_unstemmed Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
title_short Electroforming-Free Bipolar Resistive Switching Memory Based on Magnesium Fluoride
title_sort electroforming free bipolar resistive switching memory based on magnesium fluoride
topic electroforming-free
bipolar
RRAM
filamentary switching
interface
url https://www.mdpi.com/2072-666X/12/9/1049
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AT minjaekim electroformingfreebipolarresistiveswitchingmemorybasedonmagnesiumfluoride
AT jarnardhananrrani electroformingfreebipolarresistiveswitchingmemorybasedonmagnesiumfluoride
AT sungminhong electroformingfreebipolarresistiveswitchingmemorybasedonmagnesiumfluoride
AT jaehyungjang electroformingfreebipolarresistiveswitchingmemorybasedonmagnesiumfluoride