Cp∗Rh/Ag catalyzed C–H activation/cyclization sequences of NH-sulfoximines to fused aza-polyheterocycles under gentle conditions

Cp∗Rh/Ag catalyzed C–H activation/cyclization sequences of NH-sulfoximines to fused aza-polyheterocycles under gentle conditions

Disclosed herein is a novel Rh/Ag co-catalyzed SNH directed C–H activation and C–H/N–H bond functionalization protocol of free NH-sulfoximines with hypervalent iodonium ylides. With the aid of AgOTf, these C–H functionalization/cyclization sequences could be achieved at room temperature conditions....

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Bibliographic Details
Main Authors: Jiapian Huang, Fei Liu, Feihua Du, Linghui Zeng, Zhiyuan Chen
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2023-05-01
Series:Green Synthesis and Catalysis
Subjects:
Rhodium catalysis
C–H activation
Sulfoximine
Polyheterocycle
Cyclization
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554922000643

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http://www.sciencedirect.com/science/article/pii/S2666554922000643

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