Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.

Bibliographic Details
Main Authors: Sayuri Kobayashi, Tomoshige Kobayashi
Format: Article
Language:English
Published: MDPI AG 2000-09-01
Series:Molecules
Subjects:
Swern oxidation
vicinal cis-diol
α-diketone
ring-opening
norbornene
pyrazine
Online Access:http://www.mdpi.com/1420-3049/5/9/1062/

Internet

http://www.mdpi.com/1420-3049/5/9/1062/

Similar Items