Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction
An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2000-09-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/5/9/1062/ |
| _version_ | 1818906036933754880 |
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| author | Sayuri Kobayashi Tomoshige Kobayashi |
| author_facet | Sayuri Kobayashi Tomoshige Kobayashi |
| author_sort | Sayuri Kobayashi |
| collection | DOAJ |
| description | An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described. |
| first_indexed | 2024-12-19T21:32:51Z |
| format | Article |
| id | doaj.art-feef964a9c624928877d57fda9030b46 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-19T21:32:51Z |
| publishDate | 2000-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-feef964a9c624928877d57fda9030b462022-12-21T20:04:52ZengMDPI AGMolecules1420-30492000-09-01591062106710.3390/50901062Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening ReactionSayuri KobayashiTomoshige KobayashiAn improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.http://www.mdpi.com/1420-3049/5/9/1062/Swern oxidationvicinal cis-diolα-diketonering-openingnorbornenepyrazine |
| spellingShingle | Sayuri Kobayashi Tomoshige Kobayashi Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction Molecules Swern oxidation vicinal cis-diol α-diketone ring-opening norbornene pyrazine |
| title | Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction |
| title_full | Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction |
| title_fullStr | Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction |
| title_full_unstemmed | Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction |
| title_short | Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction |
| title_sort | swern oxidation of bicyclo 2 2 1 hept 5 ene 2 3 diol and its pyrazine fused derivatives an improved synthesis of bicyclo 2 2 1 hept 5 ene 2 3 dione and an unexpected ring opening reaction |
| topic | Swern oxidation vicinal cis-diol α-diketone ring-opening norbornene pyrazine |
| url | http://www.mdpi.com/1420-3049/5/9/1062/ |
| work_keys_str_mv | AT sayurikobayashi swernoxidationofbicyclo221hept5ene23diolanditspyrazinefusedderivativesanimprovedsynthesisofbicyclo221hept5ene23dioneandanunexpectedringopeningreaction AT tomoshigekobayashi swernoxidationofbicyclo221hept5ene23diolanditspyrazinefusedderivativesanimprovedsynthesisofbicyclo221hept5ene23dioneandanunexpectedringopeningreaction |