Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.

Bibliographic Details
Main Authors:	Sayuri Kobayashi, Tomoshige Kobayashi
Format:	Article
Language:	English
Published:	MDPI AG 2000-09-01
Series:	Molecules
Subjects:	Swern oxidation vicinal cis-diol ÃŽÂ±-diketone ring-opening norbornene pyrazine
Online Access:	http://www.mdpi.com/1420-3049/5/9/1062/

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