Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy

Abstract Strain engineering for gallium nitride has been studied by many researchers to improve the performance of various devices (i.e., light-emitting diodes, laser diodes, power devices, high electron mobility transistors, and so on). Further miniaturization of gallium nitride devices will clearl...

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Main Authors: Kazuma Takeuchi, Hiroyuki Ogura, Noriyuki Hasuike, Takeshi Kamikawa
Format: Article
Language:English
Published: Nature Portfolio 2024-02-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-024-53478-2
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author Kazuma Takeuchi
Hiroyuki Ogura
Noriyuki Hasuike
Takeshi Kamikawa
author_facet Kazuma Takeuchi
Hiroyuki Ogura
Noriyuki Hasuike
Takeshi Kamikawa
author_sort Kazuma Takeuchi
collection DOAJ
description Abstract Strain engineering for gallium nitride has been studied by many researchers to improve the performance of various devices (i.e., light-emitting diodes, laser diodes, power devices, high electron mobility transistors, and so on). Further miniaturization of gallium nitride devices will clearly continue in the future, and therefore an accurate understanding of the strain state in the devices is essential. However, a measurement technique for axially resolved evaluation of the strain in microareas has not yet been established. In this study, we revealed that the anisotropic strain state induced in c-plane growth gallium nitride is linked to the split state of Raman peaks, which were measured with $$z(xx)\overline{z }$$ z ( x x ) z ¯ and $$z(yx)\overline{z }$$ z ( y x ) z ¯ polarized configurations. The anisotropic strain state in c-plane gallium nitride was induced in the 3D-structure by epitaxial lateral overgrowth, which enabled successful performance of our work. This result allowed us to axially decompose the strain in c-plane gallium nitride through Raman spectroscopy and establish a measurement technique for axially resolving the strain. This measurement technique is feasible using a conventional Raman spectrometer. Furthermore, the method was indicated to be applicable to all wurtzite-type crystals, including gallium nitride, silicon carbide, and aluminum nitride. Our work provides a new perspective for understanding the complex strain state in microareas for wurtzite materials. Comprehending the strain state, which strongly affects device performance, will help promote the research and development of III-V semiconductor devices.
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spelling doaj.art-ff3b1811e81042e7a129139aee2622712024-03-05T19:12:49ZengNature PortfolioScientific Reports2045-23222024-02-0114111010.1038/s41598-024-53478-2Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopyKazuma Takeuchi0Hiroyuki Ogura1Noriyuki Hasuike2Takeshi Kamikawa3Corporate R&D Group, Keihanna Research Center, Kyocera CorporationCorporate R&D Group, Keihanna Research Center, Kyocera CorporationFaculty of Electrical Engineering and Electronics, Kyoto Institute of TechnologyCorporate R&D Group, Keihanna Research Center, Kyocera CorporationAbstract Strain engineering for gallium nitride has been studied by many researchers to improve the performance of various devices (i.e., light-emitting diodes, laser diodes, power devices, high electron mobility transistors, and so on). Further miniaturization of gallium nitride devices will clearly continue in the future, and therefore an accurate understanding of the strain state in the devices is essential. However, a measurement technique for axially resolved evaluation of the strain in microareas has not yet been established. In this study, we revealed that the anisotropic strain state induced in c-plane growth gallium nitride is linked to the split state of Raman peaks, which were measured with $$z(xx)\overline{z }$$ z ( x x ) z ¯ and $$z(yx)\overline{z }$$ z ( y x ) z ¯ polarized configurations. The anisotropic strain state in c-plane gallium nitride was induced in the 3D-structure by epitaxial lateral overgrowth, which enabled successful performance of our work. This result allowed us to axially decompose the strain in c-plane gallium nitride through Raman spectroscopy and establish a measurement technique for axially resolving the strain. This measurement technique is feasible using a conventional Raman spectrometer. Furthermore, the method was indicated to be applicable to all wurtzite-type crystals, including gallium nitride, silicon carbide, and aluminum nitride. Our work provides a new perspective for understanding the complex strain state in microareas for wurtzite materials. Comprehending the strain state, which strongly affects device performance, will help promote the research and development of III-V semiconductor devices.https://doi.org/10.1038/s41598-024-53478-2
spellingShingle Kazuma Takeuchi
Hiroyuki Ogura
Noriyuki Hasuike
Takeshi Kamikawa
Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
Scientific Reports
title Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
title_full Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
title_fullStr Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
title_full_unstemmed Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
title_short Decomposition of the anisotropic strain in 3D-structure GaN layers using Raman spectroscopy
title_sort decomposition of the anisotropic strain in 3d structure gan layers using raman spectroscopy
url https://doi.org/10.1038/s41598-024-53478-2
work_keys_str_mv AT kazumatakeuchi decompositionoftheanisotropicstrainin3dstructureganlayersusingramanspectroscopy
AT hiroyukiogura decompositionoftheanisotropicstrainin3dstructureganlayersusingramanspectroscopy
AT noriyukihasuike decompositionoftheanisotropicstrainin3dstructureganlayersusingramanspectroscopy
AT takeshikamikawa decompositionoftheanisotropicstrainin3dstructureganlayersusingramanspectroscopy