Structure-reactivity analysis of novel hypervalent iodine reagents in S-vinylation of thiols

The transition-metal free S-vinylation of thiophenols by vinylbenziodoxolones (VBX) constituted an important step forward in hypervalent iodine-mediated vinylations, highlighting the difference to vinyliodonium salts and that the reaction outcome was influenced by the substitution pattern of the ben...

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Bibliographic Details
Main Authors: Sayad Doobary, Ester Maria Di Tommaso, Alexandru Postole, A. Ken Inge, Berit Olofsson
Format: Article
Language:English
Published: Frontiers Media S.A. 2024-02-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2024.1376948/full