Time-dependent ion selectivity in capacitive charging of porous electrodes

In a combined experimental and theoretical study, we show that capacitive charging of porous electrodes in multicomponent electrolytes may lead to the phenomenon of time-dependent ion selectivity of the electrical double layers (EDLs) in the electrodes. This effect is found in experiments on capacit...

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Bibliographic Details
Main Authors: Zhao, R., van Soestbergen, M., van der Wal, A., Rijnaarts, H. H. M., Bazant, Martin Z., Biesheuvel, P. M.
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:en_US
Published: Elsevier 2016
Online Access:http://hdl.handle.net/1721.1/101160