Strategies to Avert Electrochemical Shock and Their Demonstration in Spinels

We demonstrate that extensive electrochemical shock–electrochemical cycling induced fracture–occurs due to coherency stresses arising from first order cubic-to-cubic phase transformations in the spinels LiMn[subscript 2]O[subscript 4] and LiMn[subscript 1.5]Ni[subscript 0.5]O[subscript 4]. Electroch...

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Bibliographic Details
Main Authors: Woodford, William H., Carter, W. Craig, Chiang, Yet-Ming
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:en_US
Published: Electrochemical Society 2016
Online Access:http://hdl.handle.net/1721.1/101765
https://orcid.org/0000-0001-7564-7173
https://orcid.org/0000-0002-0833-7674