Stereospecific Ring-Opening Metathesis Polymerization of Norbornadienes Employing Tungsten Oxo Alkylidene Initiators

Stereospecific Ring-Opening Metathesis Polymerization of Norbornadienes Employing Tungsten Oxo Alkylidene Initiators

We report here the polymerization of several 7-isopropylidene-2,3-disubstituted norbornadienes, 7-oxa-2,3-dicarboalkoxynorbornadienes, and 11-oxa-benzonorbornadienes with a single tungsten oxo alkylidene catalyst, W(O)(CH-t-Bu)(OHMT)(Me2Pyr) (OHMT = 2,6-dimesitylphenoxide; Me2Pyr = 2,5-dimethylpyrro...

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Bibliographic Details
Main Authors: Forrest, William P., Weis, Jonathan Garrett, John, Jeremy M., Axtell, Jonathan, Simpson, Jeffrey H., Swager, Timothy M., Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2016
Online Access:http://hdl.handle.net/1721.1/104039
https://orcid.org/0000-0002-7405-6811
https://orcid.org/0000-0001-5827-3552

Internet

http://hdl.handle.net/1721.1/104039
https://orcid.org/0000-0002-7405-6811
https://orcid.org/0000-0001-5827-3552

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