Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues

Multinuclear solid-state nuclear magnetic resonance, mass spectrometry, first-principles molecular dynamics simulations, and other complementary evidence reveal that the coordination environment around the Zn2+ ions in MOF-5, one of the most iconic materials among metal–organic frameworks (MOFs), is...

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Bibliographic Details
Main Authors: Bellarosa, Luca, López, Núria, Brozek, Carl Kavanaugh, Michaelis, Vladimir K., Ong, Ta-Chung, Griffin, Robert Guy, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2016
Online Access:http://hdl.handle.net/1721.1/105161
https://orcid.org/0000-0002-6708-7660
https://orcid.org/0000-0003-1589-832X
https://orcid.org/0000-0002-1262-1264