Formation of Alternating trans-A-alt-B Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Imido Alkylidene Complexes

Ring-opening metathesis polymerization (ROMP) is used to prepare trans-poly(A-alt-B) polymers from a 1:1 mixture of A and B where A is a cyclic olefin such as cyclooctene (A[subscript 1]) or cycloheptene (A[subscript 2]) and B is a large norbornadiene or norbornene derivative such as 2,3-dicarbometh...

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Bibliographic Details
Main Authors: Jeong, Hyangsoo, John, Jeremy M, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2016
Online Access:http://hdl.handle.net/1721.1/105182
https://orcid.org/0000-0002-1788-4100
https://orcid.org/0000-0002-7405-6811
https://orcid.org/0000-0001-5827-3552