Concise Total Synthesis of (+)-Asperazine, (+)-Pestalazine A, and (+)-iso-Pestalazine A. Structure Revision of (+)-Pestalazine A
The concise, enantioselective total syntheses of (+)-asperazine (1), (+)-iso-pestalazine A (2), and (+)-pestalazine A (3) have been achieved by the development of a late-stage C3–C8′ Friedel–Crafts union of polycyclic diketopiperazines. Our modular strategy enables the union of complex polycyclic di...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society
2017
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| Online Access: | http://hdl.handle.net/1721.1/107391 https://orcid.org/0000-0002-4426-7474 https://orcid.org/0000-0002-5585-9280 https://orcid.org/0000-0003-3080-1063 |