A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

Dibenzo-7-phosphanorbornadiene Ph[subscript 3]PC(H)PA (1, A = C[subscript 14]H[subscript 10], anthracene) is reported here as a molecular precursor to phosphaethyne (HC≡P), produced together with anthracene and triphenylphosphine. HCP generated by thermolysis of 1 has been observed by molecular beam...

Full description

Bibliographic Details
Main Authors: Martin-Drumel, Marie-Aline, Hou, Gao-Lei, Wang, Xue-Bin, McCarthy, Michael C., Transue, Wesley, Velian, Alexandra, Nava, Matthew Jordan, Womack, Caroline C., Jiang, Jun, Field, Robert W, Cummins, Christopher C.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2017
Online Access:http://hdl.handle.net/1721.1/107727
https://orcid.org/0000-0001-7445-5663
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0002-3526-3797
https://orcid.org/0000-0002-7609-4205
https://orcid.org/0000-0003-2568-3269

Internet

http://hdl.handle.net/1721.1/107727
https://orcid.org/0000-0001-7445-5663
https://orcid.org/0000-0002-9239-7505
https://orcid.org/0000-0002-3526-3797
https://orcid.org/0000-0002-7609-4205
https://orcid.org/0000-0003-2568-3269

Similar Items